Reference Study [ HLCT Materials] TPP-TXO2

Caixia Fu,a) Shuai Luo,a) Zhenzhen Li,b) Xin Ai,c) Zhenguo Pang,a) Chuan Li,a)
Kuan Chen,a) Liang Zhou,b) Feng Li,c) Yan Huang,a) and Zhiyun Lu,a)

a) Key Laboratory of Green Chemistry and Technology (Ministry of Education),
College of Chemistry, Sichuan University, Chengdu 610064, China.
b )State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of
Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China.
c )State Key Laboratory of Supramolecular Structure and Materials,
College of Chemistry, Jilin University, Changchun, 130012, China.

Reference: Chem. Commun., 2019, 55, 6317--6320


  • A new family of hybridized local and charge-transfer (HLCT) emitters bearing a pyrene structural unit has been made for deep-blue OLED device.
  • Deep-blue OLEDs based on them achieved high brightness over 10000 cd m-2, high maximum external quantum efficiency over 10.5%, and high maximum exciton utilization efficiency approaching 100%, with CIE coordinates of (0.152, 0.065).

Materials & Devices

Device: ITO/HAT-CN (6 nm)/HAT-CN (0.2 wt%):TAPC (50 nm)/ TPP-TXO2:TcTa (12 wt%, 10 nm)/emitter:26DCzPPy (12 wt%, 10 nm)/Tm3PyP26PyB (50 nm)/LiF (1 nm)/Al (100 nm)

*Fig.3  reference source: Chem. Commun., 2019, 55, 6317--6320
TPP-TXO2, HLCT, hybridized local, charge-transfer, Blue OLED

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